Dislocation Networks in Folded-Chain Polyethylene Crystals
V. F. Holland 1 and
P. H. Lindenmeyer 1
1 Chemstrand Research Center, Inc., Durham, North Carolina
Interaction between the fold surfaces of polymer crystals can be strong enough to concentrate any mismatch in orientation into a network of dislocations. Direct observation of these networks by diffraction contrast electron microscopy yields strong evidence in favor of polymer crystallization by a regular chain-folding mechanism.