Superconducting Metastable Compounds
H. L. Luo 1,
M. F. Merriam 2, and
D. C. Hamilton 2
1 W. M. Keck Laboratory of Engineering Materials, California Institute of Technology, Pasadena
2 Department of Physics and Institute for the Study of Matter, University of California, San Diego, La Jolla
A number of metastable phases, germanides and tellurides of gold and silver, have been prepared, analyzed by x-ray diffraction, and investigated for superconductivity. The new superconductors and their transition temperatures are AgTe3 (2.6°K), Ag4Ge (0.85°K), Au3Te5 (1.62°K), and Au1-xGex (0.99°K-1.63°K) where (0.27
x
0.60). Au-Ge compositions with other values of x do not superconduct above 0.32°K.