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Originally published in Science Express on 14 August 2008
Science 19 September 2008:
Vol. 321. no. 5896, pp. 1658 - 1660
DOI: 10.1126/science.1162193

Reports

Polymer Pen Lithography

Fengwei Huo,1,2* Zijian Zheng,1,2* Gengfeng Zheng,1,2 Louise R. Giam,2,3 Hua Zhang,1,2{dagger} Chad A. Mirkin1,2,3{ddagger}

We report a low-cost, high-throughput scanning probe lithography method that uses a soft elastomeric tip array, rather than tips mounted on individual cantilevers, to deliver inks to a surface in a "direct write" manner. Polymer pen lithography merges the feature size control of dip-pen nanolithography with the large-area capability of contact printing. Because ink delivery is time and force dependent, features on the nanometer, micrometer, and macroscopic length scales can be formed with the same tip array. Arrays with as many as about 11 million pyramid-shaped pens can be brought into contact with substrates and readily leveled optically to ensure uniform pattern development.

1 Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208–3113, USA.
2 International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208–3113, USA.
3 Department of Materials Science and Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208–3113, USA.

* These authors contributed equally to this work.

{dagger} Current address: School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.

{ddagger} To whom correspondence should be addressed. E-mail: chadnano{at}northwestern.edu

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Science. ISSN 0036-8075 (print), 1095-9203 (online)